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Reactivity of aminopyrroles: Protonation
Authors:Girolamo Cirrincione  Anna Maria Almerico  Patrizia Diana  Paola Barraja  Francesco Mingoia  Stefania Grimaudo  Gaetano Dattolo  Enrico Aiello
Abstract:The behaviour of 2- and 3-aminopyrroles towards protonation is similar. In dimethyl sulphoxide/trifluoroacetic acid they are protonated at the exocyclic nitrogen, whereas in pure trifluoroacetic acid, protonation at the 5- and/or 3-position of the ring takes place.
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