Zum System Zn/Mo/O. I. Phasenbestand und Eigenschaften der ternären Zinkmolybdate; Struktur von Zn3Mo2O9 |
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| Authors: | T Shnel W Reichelt H Oppermann Hj Mattausch A Simon |
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| Institution: | T. Söhnel,W. Reichelt,H. Oppermann,Hj. Mattausch,A. Simon |
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| Abstract: | On the System Zn/Mo/O. I. Phases and Properties of Ternary Zinc Molybdates; Crystal Structure of Zn3Mo2O9 Several ternary compounds are known in the Zn/Mo/O-system. The phases ZnMoO4, Zn2Mo3O8 and Zn3Mo2O9 are stable at 900°C. The coexistence ranges are shown in the ternary phase diagram. The structure of Zn3Mo2O9 has been determined by single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P21/m (a = 7,757(1) Å, b = 7,132(1) Å, c = 8,370(2) Å, β = 117,40(1)º, Z = 2). |
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| Keywords: | Phase investigation phase diagram crystal structure differential thermo analysis zinc molybdate |
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