Eisen-Zweikernkomplexe mit unterschiedlichen P4-Liganden |
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Authors: | O. J. Scherer,G. Schwarz,G. Wolmersh user |
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Affiliation: | O. J. Scherer,G. Schwarz,G. Wolmershäuser |
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Abstract: | Dinuclear Iron Complexes with Different P4 Ligands The photolysis of [Cp″Fe(CO)2]2 1 (Cp″ = C5H3tBu2-1,3) and P4 gives with successive cleavage of P? P bonds and decarbonylation the P4 complex series [Cp″2Fe2P4(CO)4 ? n] 2 (n = O), 3 (n = 1), 4 (n = 2), 5 (n = 3) and 6 (n = 4) with different P4 ligands. 4 and 6 have been further characterized by X-ray structure analyses. |
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Keywords: | Dinuclear iron P4 complexes bicyclic, cyclic and acyclic P4 coordination modes |
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