Zur Chemie des Dimesityleisens. X. Mesityleisenkomplexe [FeMes(X)]2 mit zentraler {Fe2(μ-Mes)2}-Einheit (Mes = C6H2-2,4,6-(CH3)3) |
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| Authors: | H. Mü ller,W. Seidel,H. G rls |
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| Affiliation: | H. Müller,W. Seidel,H. Görls |
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| Abstract: | Chemistry of Dimesityl Iron. X. Mesityl Iron Complexes [FeMes(X)]2 with a Central {Fe2(μ-Mes)2} Unit (Mes = C6H2-2,4,6-(CH3)3) Dimeric complexes [{MesFe(OAryl)}2] with coordination number (CN) of 3 are obtained from Fe2Mes4 1 by partial acidolyses with 2,6-di-tert-butyl-substituted phenols (HOAryl). 1 reacts with 1,3-diketones in a molar ratio of 1:2 to [{MesFe(diketonate)}2] with CN 4. A central {Fe2(μ-Mes)2}-unit with short Fe—Fe distances of 2.56 to 2.63 Å ( 1: 2.615 Å) is found in both types of complexes. The mixed ligand complexes react with an excess of phenol or diketone to {Fe(OAryl)2} or {Fe(diketonate)2}, respectively. 1 reacts with HOAryl in the molar ratio of 1:1 to [Fe2(μ-Mes)2Mes(OAryl)]. The structures of [Fe2(μ-Mes)2(OC6H2-2,6-tBu2-4-CH3)2] ( 3 ), [Fe2(μ-Mes)2Mes(OC6H2-2,4,6-tBu3)] ( 5 ) and [Fe2(μ-Mes)2{(tBuCO)2CH}2] ( 9 ) are presented. |
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| Keywords: | Dimesityl iron aryloxide complexes diketonate complexes crystal structure |
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