Metallsubstituierte Phosphaalkene und Acylphosphane. 31. Zur Reaktivität von (η5-C5Me5)(CO)2FeP = C(NMe2)2 gegenüber Zinndichlorid. Röntgenstrukturanalyse von {(η5-C5Me5)[η1-(Me2N)2C = P?P = C(NMe2)2](CO)2Fe}+{[Me2N)2C]2P}+(FeCl4)2− |
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| Authors: | Lothar Weber Jens-Martin Quasdorff Hans-Georg Stammler Beate Neumann |
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| Abstract: | Transition-Metal Substituted Phosphaalkenes and Acyl Phosphanes. 31 1] Reactivity of (η5-C5Me5)(CO)2FeP = C(NMe2)2 towards Tin Dichloride. X-Ray Structure Analysis of {(η5-C5Me5)η1-(Me2N)2C = P? P = C(NMe2)2](CO)2Fe}+{Me2N)2C]2P}+(FeCl4)2? Reaction of metallophosphaalkene (η5-C5Me5)(CO)2 · FeP = C(NMe2)2 ( 1 ) with anhydrous tin dichloride affords the salt-like compound {(η5-C5Me5)η1-(Me2N)2C = P? P = C(NMe2)2] · (CO)2Fe}+{(Me2N)2C]2P}+(FeCl4)2? 5 which is characterized by single crystal X-ray analysis and spectra (IR, 1H, 31P-NMR). |
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| Keywords: | Metallophosphaalkenes Transition Metal Complexes X-Ray Structure Analysis |
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