Abstract: | Structural Chemistry and Impedance Spectroscopy of Mg2+ stabilized Na+/Pr3+-β″-Aluminas The structure with the ionic distribution in the conduction planes of a Pr3+-exchanged Mg2+ stabilized Na+-β″-alumina crystal, composition determined by electron microprobe analysis to Na1.19Pr0.13Mg0.49Al10.49O17 (degree of exchange ξ = 25%, related to Na+ content), has been investigated by single crystal X-ray diffraction methods at room temperature (R3 m, Z = 3, a = 561.8(2) pm, c = 3 361.5(11) pm). Pr3+ is slightly shifted in the ab-plane from the centrosymmetric 9 d (mO) into a 18 h site. Na+ occupies 18 h as well as 6 c (BR) positions. Ionic conductivity data of Mg2+ stabilized Na+/Pr3+-β″-Al2O3 crystals with varying degree of exchange determined by impedance spectroscopy are given in an Arrhenius diagram. With growing Pr3+ content the conductivity σ decreases with increasing activation energy. |