Synthesen und Charakterisierung von [Ni(tBuAs)6] und [Pd(tBuAs)6] |
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| Authors: | Evamarie Hey-Hawkins Maren Pink Hannes Oesen Dieter Fenske |
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| Abstract: | Syntheses and Characterization of [Ni(tBuAs)6] and [Pd(tBuAs)6] The reduction of tBuAsCl2 with magnesium in the presence of NiCl2 or PdCl2 yields the complexes [Ni(tBuAs)6] ( 2 ) and [Pd(tBuAs)6] ( 3 ). The structure of ( 2 ) was determined by X-ray single crystal structure analysis. ( 2 ) consists of the sixmembered ring (tBuAs)6 in chair conformation with the nickel atom in the center of this ring. |
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| Keywords: | Cyclohexaarsine ligand transition metal complexes crystal structure |
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