K11[HSn(PWO34)2] · 27 H2O – Synthese und Struktur |
| |
| Authors: | Alexandru Botar Bogdan Botar Pedro Gili Achim Müller Jochen Meyer Hartmut Bgge Marc Schmidtmann |
| |
| Institution: | Alexandru Botar,Bogdan Botar,Pedro Gili,Achim Müller,Jochen Meyer,Hartmut Bögge,Marc Schmidtmann |
| |
| Abstract: | K11HSn  (PW  O34)2] · 27 H2O – Synthesis and Structure K11HSn (PW O34)2] · 27 H2O 1 can be synthesized in an “one-pot reaction” from commercially obtainable educts (SnCl2; Na2HPO4 · 7 H2O, Na2WO4 · 2 H2O) in high yields and has been characterized by elemental analysis, IR/Raman-, UV/Vis-spectroscopy as well as by X-ray crystal structure analysis. The example of 1 again demonstrates the validity of our working hypothesis, that polyoxometalates can be obtained by linking highly charged, transferable building blocks by cationic centres within the scope of an optimal charge control. For structural details see “Inhaltsübersicht”. |
| |
| Keywords: | Tin(II)tungstophosphate polyoxometalate |
|
|
