| [Cd（SS）（NN）]配合物掺杂CdS的光-电转换特性 |
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| 引用本文： | 潘庆才,沈红旗,李伟,彭正合.[Cd（SS）（NN）]配合物掺杂CdS的光-电转换特性[J].化学研究与应用,2008,20(4):407-410. |
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| 作者姓名： | 潘庆才 沈红旗 李伟 彭正合 |
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| 作者单位： | 1. 黄淮学院化学化工系,河南,驻马店,463000
2. 武汉大学化学与分子科学学院,湖北,武汉,430072 |
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| 基金项目： | 国家自然科学基金
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河南省教育厅自然科学基金 |
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| 摘 要： | 本文报道了配合物Cd(SS)(NN)](SS=mnt2-,1,2-二氰基乙烯-1,2-二硫醇离子.NN=phen-5,6-dione,1,10-菲咯啉-5,6-二酮)的合成.探讨了Cd(SS)(NN)的电子吸收光谱和发射光谱。研究了掺杂有配合物Cd(SS)(NN)的CdS复合膜的光-电转换特性。
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| 关 键 词： | 二硫纶 二亚胺 镉 配合物 光电转换 |
| 文章编号： | 1004-1656(2008)04-0407-04 |
| 修稿时间： | 2007年9月4日 |
Characteristics of photoelectric change-over of CdS doped with complexes [Cd(SS)(NN)] |
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| PAN Qing-cai,SHEN Hong-qi,LI Wei,PENG Zheng-he.Characteristics of photoelectric change-over of CdS doped with complexes [Cd(SS)(NN)][J].Chemical Research and Application,2008,20(4):407-410. |
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| Authors: | PAN Qing-cai SHEN Hong-qi LI Wei PENG Zheng-he |
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| Abstract: | The Synthesis of complexes Cd(SS)(NN)](SS= mnt2-,1,2-dicyano-1,2-ethylenedithiolate or maleonitriledithiolate.NN= phen-5,6-dione,1,10-phenanthroline5,6-dione) was reported.The electronic absorption spectra and emission spectra of title complex were determined.The complex Cd(SS)(NN)] exhibit strong absorption spectra bands at 272~488nm in DMSO and DMF and emission spectra bands at 370~506nm in DMF.The dark conductivity and photoconductivity of CdS doped with complexes Cd(SS)(NN)] were ascertained.The correlation between photosensitization of complex Cd(SS)(NN)] to CdS and its electronic spectra was studied. |
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| Keywords: | dithiolene phenanthroline-5 6-dione cadmium complex photosensitization |
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