| 金属蒸气合成在金属有机合成中的应用 |
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| 引用本文： | 王序昆,黄唯平,吴世华.金属蒸气合成在金属有机合成中的应用[J].有机化学,1992,12(1):14-25. |
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| 作者姓名： | 王序昆 黄唯平 吴世华 |
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| 作者单位： | 南开大学元素有机化学研究所，南开大学元素有机化学研究所，南开大学化学系 天津 300071，天津 300071，天律 300071 |
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| 摘 要： | 本文简要地介绍了金属蒸气合成法的基本原理、仪器和实验技术, 并按金属原子分别与炔、单烯、多烯、环烯、芳烃体系、卤代烃、有机混和物的反应及有机金属硼化合物的合成, 对金属蒸气合成法在金属有机合成中的应用进行了讨论。
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| 关 键 词： | 凝聚 有机硼化合物 合成法 溶剂化 元素有机化学 金属蒸气 金属原子 |
Application of metal vapor synthesis in organometallic synthesis |
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| WANG Xu-Kun,HUANG Wei-Ping WU Shi-Hua Institute of Elemento-Organic Chemistry,Nankai University ,Tianjin.Application of metal vapor synthesis in organometallic synthesis[J].Chinese Journal of Organic Chemistry,1992,12(1):14-25. |
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| Authors: | WANG Xu-Kun HUANG Wei-Ping WU Shi-Hua Institute of Elemento-Organic Chemistry Nankai University Tianjin |
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| Institution: | WANG Xu-Kun,HUANG Wei-Ping WU Shi-Hua Institute of Elemento-Organic Chemistry,Nankai University 300071,Tianjin Department of Chemistry,Nankai University,300071,Tianjin |
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| Abstract: | This paper briefly describes the fundamental principle. apparatus, and laboratorytechniques of Metal Vapor Synthesis (MVS). The application of MVS in Organometallic Syn-thesis has been reviewed according to the metal atoms reaction with alkyne, alkene, polyene,cycloene, aromatic system. halohydrocarbon and mixed organic compounds respectively. as wellas the synthesis of Organometallaboron compounds. |
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| Keywords: | metal vapor synthesis organometallic synthesis cocondensation solvated metal atoms |
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