Synthesis and structure of a stabilized 10-membered cyclic enediyne |
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| Authors: | Pitsch Wolfgang Klein Michael Zabel Manfred König Burkhard |
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| Institution: | Institut für Organische Chemie, Universit?t Regensburg, D-93040 Regensburg, Germany. |
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| Abstract: | The synthesis and structure of an acetal protected 10-membered cyclic enediyne-1,2-diol rac-10 is reported. The conformational constrain of the unsaturated macrocycle by the acetal protection group prevents the thermal cyclization reaction of the endiyne during synthesis and purification. |
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