Towards models of the oxygen-evolving complex (OEC) of photosystem II: a Mn4Ca cluster of relevance to low oxidation states of the OEC |
| |
| Authors: | Koumousi Evangelia S Mukherjee Shreya Beavers Christine M Teat Simon J Christou George Stamatatos Theocharis C |
| |
| Affiliation: | Department of Chemistry, University of Patras, 26500 Patras, Greece. |
| |
| Abstract: | Synthetic access has been achieved into high oxidation state Mn/Ca chemistry with the 4?:?1 Mn?:?Ca stoichiometry of the oxygen-evolving complex (OEC) of plants and cyanobacteria; the anion of (Et(3)NH)(2)[Mn(III)(4)Ca(O(2)CPh)(4)(shi)(4)] has a square pyramidal metal topology and an S = 0 ground state. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
