Characterization of a synthetic peroxodiiron(III) protein model complex by nuclear resonance vibrational spectroscopy |
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| Authors: | Do Loi H Wang Hongxin Tinberg Christine E Dowty Eric Yoda Yoshitaka Cramer Stephen P Lippard Stephen J |
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| Institution: | Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA. |
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| Abstract: | The vibrational spectrum of an η(1),η(1)-1,2-peroxodiiron(III) complex was measured by nuclear resonance vibrational spectroscopy and fit using an empirical force field analysis. Isotopic (18)O(2) labelling studies revealed a feature involving motion of the {Fe(2)(O(2))}(4+) core that was not previously observed by resonance Raman spectroscopy. |
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