Structure of the trimer of acrolein diethyl acetal |
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Authors: | S. S. Yufit V. F. Kucherov |
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Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR |
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Abstract: | Summary The product formed by the condensation of acrolein diethyl acetal under the influence of BF3 etherate is a trimer of composition C21H42O6 and is 2-ethoxy-4-(1-ethoxyallyl)glutaraldehyde diethyl acetal. A mechanism is proposed for its formation via a quasi-aromatic complex with subsequent cyclic electron transfer. |
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