Normal- and Reversed-Phase Behaviour of 16,17-Secoestrone Derivatives on Cyanopropyl-Bonded Silica Gel |
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| Authors: | Marijana M A?anski Jelena P Dobrijevi? Azra S Red?epovi? ?ura N Vuji? Suzana S Jovanovi?-?anta |
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| Institution: | 1. Department of Applied and Engineering Chemistry, Faculty of Technology, University of Novi Sad, Bulevar cara Lazara 1, 21000, Novi Sad, Serbia
2. Institute of Chemistry, Faculty of Science, University of Novi Sad, Trg Dositeja Obradovi?a 3, 21000, Novi Sad, Serbia
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| Abstract: | The retention behaviour of a number of 16,17-secoestrone derivatives has been studied by LC and HPTLC on a polar cyanopropyl-bonded stationary phase using non-aqueous and aqueous-organic mobile phases. The retention behaviour has been discussed in terms of nature of the solute, eluent and stationary phase. The correlation between retention constants of 16,17-secoestrone derivatives obtained from reversed-phases and commercially available ACD log P software (Advanced Chemistry, Toronto, Canada) has also been examined. |
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