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The first total synthesis of (+)-mucosin
Authors:Henderson Alan R  Stec Jozef  Owen David R  Whitby Richard J
Affiliation:Chemistry, University of Southampton, Southampton, Hampshire SO17 1BJ, UK.
Abstract:The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core.
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