The first total synthesis of (+)-mucosin |
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Authors: | Henderson Alan R Stec Jozef Owen David R Whitby Richard J |
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Affiliation: | Chemistry, University of Southampton, Southampton, Hampshire SO17 1BJ, UK. |
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Abstract: | The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core. |
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