Synthesis of kinetically stabilized 1,2-dihydrodisilenes |
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Authors: | Agou Tomohiro Sugiyama Yusuke Sasamori Takahiro Sakai Heisuke Furukawa Yukio Takagi Nozomi Guo Jing-Dong Nagase Shigeru Hashizume Daisuke Tokitoh Norihiro |
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Institution: | Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan. |
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Abstract: | Kinetically stabilized 1,2-dihydrodisilenes were successfully synthesized and isolated by the introduction of sterically protecting bulky aryl groups. These 1,2-dihydrodisilenes exhibit distinct Si═Si double-bond character in both solution and the solid state. The Si-H bonds in these 1,2-dihydrodisilenes exhibit higher s character than those of typical σ(4),λ(4)-hydrosilanes. Moderate heating of these 1,2-dihydrodisilenes in solution resulted in their isomerization to the corresponding trihydrodisilanes, with an intramolecular hydrogen migration as the rate-determining step. |
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