Alkylation of benzene with 4-methylcyclohexanol in the presence of sulfuric acid |
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| Authors: | V. G. Lipovich V. V. Zemskov G. V. Ratovskii O. V. Burlakova |
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| Affiliation: | (1) Institute of High Temperatures, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Alkylation of benzene with 4-methylcyclohexanol in the presence of methylcyclohexane and 96, 88, and 80% H2SO4 has been studied. It was established that depending on the solubility of the starting components in sulfuric acid, alkylation occurs in the inorganic phase or on the interface between the organic and inorganic phases. The yield and composition of the catalysate are determined to a significant degree by the extent of the alkylation process and intramolecular hydride transfers.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 121–125, January, 1990. |
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