| Solid-state electrochemiluminescence of a novel iridium（Ⅲ） complex |
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| 作者姓名： | Shu Quan Sun Qi Jun Song He Fang Yuan Yu Qiang Ding |
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| 作者单位： | School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China （No. 20571033）. |
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| 摘 要： | The solid-state ECL behavior of a water-insoluble bis-cyclometalated （pq）2Ir（N-phMA） complex is presented, in which pq is a 2-phenylquinoline anion and N-phMA is N-phenyl methacrylamide, a monoanionic bidentate ligand. The MWNTs/（pq）2Ir（N-phMA） film, MWNTs/Ru（bpy）3^2＋ film and （pq）2Ir（N-phMA） directly modified glassy carbon electrode were fabricated; only the MWNTs/（pq）2Ir（N-phMA） film can produce steady ECL in the presence of tri-n-propylamine as a coreactant.
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| 关 键 词： | 钴胺素 抗贫血药物 联吡啶钌 配合物 制法 |
| 收稿时间： | 2 June 2008. |
Solid-state electrochemiluminescence of a novel iridium(III) complex |
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| Shu Quan Sun Qi Jun Song He Fang Yuan Yu Qiang Ding.Solid-state electrochemiluminescence of a novel iridium(III) complex[J].Chinese Chemical Letters,2008,19(12):1509-1512. |
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| Authors: | Shu Quan Sun Qi Jun Song He Fang Yuan Yu Qiang Ding |
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| Institution: | School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China |
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| Abstract: | The solid-state ECL behavior of a water-insoluble bis-cyclometalated (pq)2Ir(N-phMA) complex is presented, in which pq is a 2-phenylquinoline anion and N-phMA is N-phenyl methacrylamide, a monoanionic bidentate ligand. The MWNTs/(pq)2Ir(N-phMA) film, MWNTs/Ru(bpy)32+ film and (pq)2Ir(N-phMA) directly modified glassy carbon electrode were fabricated; only the MWNTs/(pq)2Ir(N-phMA) film can produce steady ECL in the presence of tri-n-propylamine as a coreactant. |
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| Keywords: | Solid-state electrochemiluminescence Iridium(III) complex Multi-wall carbon nanotubes |
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