| 酰氨基硫脲及有关的杂环衍生物的研究 I:1-氰乙酰基-4-芳基氨基硫脲及有关的杂环衍生物的合成 |
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| 引用本文： | 张自义,杨虎,高东哲.酰氨基硫脲及有关的杂环衍生物的研究 I:1-氰乙酰基-4-芳基氨基硫脲及有关的杂环衍生物的合成[J].化学学报,1987,45(4):403-407. |
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| 作者姓名： | 张自义 杨虎 高东哲 |
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| 作者单位： | 兰州大学化学系;北京结核病院 |
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| 摘 要： | 合成了九个1-氰乙酰基-4-芳基氨基硫脲类化合物和四个3-氰甲基-4-芳基-1,2,4-三唑啉与硫酮类化合物和四个2-苯基氨基-5-取代-1,3-噻二唑类化合物.并初步研究了这些化合物的抗结核菌活性和植物生长促进作用.
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| 关 键 词： | 硫酮 氮杂环化合物 植物生长调节剂 噻二唑P 三唑P 硫氰酸酯 氰乙酸P 氨基硫脲P 酰肼P |
Studies on the acylthiosemicarbazides and related heterocyclic derivatives I: Synthesis of 1-cyanoacetyl-4-aryl-thiosemicarbazides and related heterocyclic derivatives |
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| ZHANG ZIYI,YANG HU,GAO DONGZHE.Studies on the acylthiosemicarbazides and related heterocyclic derivatives I: Synthesis of 1-cyanoacetyl-4-aryl-thiosemicarbazides and related heterocyclic derivatives[J].Acta Chimica Sinica,1987,45(4):403-407. |
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| Authors: | ZHANG ZIYI YANG HU GAO DONGZHE |
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| Abstract: | Refluxing NCCH2CONHNH2 with RNCS (R = Ph, 4-MeOC6H4, 4-ClC6H4, 3-BrC6H4, 4-MeC6H4, 1-naphthyl, 2-naphthyl, 4-BrC6H4, 3,4-Me2C6H3) in EtOH gave NCCH2CONHNHC(S)NHR (I). Cyclization of I (R = Ph, 4-MeOC6H4, 4-MeC6H4, 3,4-Me2C6H2) with aqueous K2CO3 gave triazolinethiones II, whereas cyclization of I (R = Ph) with concentrated H2SO4 gave thiadiazoles III (R1 = NCCH2, H2NCOCH2). |
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| Keywords: | THIOKETONE NITROGEN HETEROCYCLICS PLANT GROWTH REGULATORS THIADIAZOLE P PYRRODIAZOLE P THIOCYANIC ACID ESTER CYANOACETIC ACID P THIOSEMICARBAZIDE P HYDRAZIDE P |
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