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Asymmetrical Conductivity of TCNQ Modificd Au/Thiol-Lipid Bilayers in Fe(CN)_6~(3-/4-)solution
Authors:Peng DIAO   Dian Lu JIANG   Xiao Li CUI   Deng Ping GU  Ru Ting TONG   Bing ZHONG
Affiliation:Peng DIAO; Dian Lu JIANG; Xiao Li CUI; Deng Ping GU;Ru Ting TONG; Bing ZHONG(Department of Chemistry. Hebei Teacher's University. Shijiazhuang 050016)(Institute of Coal Chemistry. Chinese Academy of Sciences. Taiyuan 030001)
Abstract:In this work. elcctron transfer across Au supported octadecanethiolphosphatidyl choline (Au/ODT-PC) bilayers, which were modified with 7.7.8.8-tetracyanoquinodimethane (TCNQ). were investigated using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). Results of EIS experiments show that the TCNQ molecules act as electron conductors in the bilayer. Cyclic voltammetry indicates that the TCNQ modified Au/thiol-lipid bilayers display strong asymmetrical conductivity in Fe(CN)3-/4-6 solution.
Keywords:Electrochemistry  supported bilayer  electrochemical impedance spectroscopy  cyclic voltammetry  asymmetrical conductivity
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