Thermodynamic properties of lanthanum molybdates |
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Authors: | Yu L Suponitskiy O P Proshina A G Dyunin S E Liashenko |
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Institution: | 1. Mendeleev University of Chemical Technology of Russia, Moscow, 125047, Russia 2. Moscow State Forest University, Mytishchi, Moscow oblast, 141005, Russia
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Abstract: | The enthalpy of solution of LаОНMoO4 and Cs2MoO4 in aqueous HCl at 298 К has been determined by solution calorimetry, and the standard enthalpy of formation of lanthanum hydroxomolybdate has been calculated. The enthalpies of solution of NaLa(MoO4)2 and Na5Lа(MoO4)4 in molybdate melt at 973 K have been determined by high-temperature melt solution microcalorimetry, and the high-temperature enthalpies of the double molybdates in the 298–1000 K range have been measured by the mixing method. The standard enthalpies of formation of the double molybdates have been calculated using data available from the literature. The low-temperature heat capacity of NaLa(MoO4)2 in the 60–300 K range has been measured on an adiabatic vacuum calorimeter. The basic thermodynamic properties of NaLa(MoO4)2, Na5Lа(MoO4)4, and LаОНMoO4 have been calculated. |
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