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| 微波合成PtRu/C纳米催化剂及其对甲醇电化学氧化性能 | |
| 引用本文： | 陈卫祥,俞贵艳,赵 杰,LEE Jim-Yang,刘昭林. 微波合成PtRu/C纳米催化剂及其对甲醇电化学氧化性能[J]. 无机化学学报, 2004, 20(12): 1467-1470 |
| 作者姓名： | 陈卫祥 俞贵艳 赵 杰 LEE Jim-Yang 刘昭林 |
| 作者单位： | 1. 浙江大学化学系,杭州,310027;新加坡国立大学,新加坡-麻省理工学院联合体,117576,新加坡 2. 浙江大学化学系,杭州,310027 3. 新加坡国立大学,新加坡-麻省理工学院联合体,117576,新加坡;新加坡国立大学,化学与环境工程系,119260,新加坡;新加坡材料研究与工程所,117602,新加坡 4. 新加坡材料研究与工程所,117602,新加坡 |
| 基金项目： | 国家自然科学基金资助项目(No.50171063,20003009)，浙江省自然科学基金资助项目(No.200053)，MEBCSProgrammeofSingapore鄄MITAlliance资助项目 |
| 摘 要： | PtRu/carbon nanosized catalyst with PtRu loading of 26.4wt% (Rt∶Ru=1.0∶1.0～1.1) was rapidly synthesized by the microwave polyol process employing the ethylene glycol solution of H2PtCl6 and RuCl3 as precursors in the presence of XC-72 carbon support. TEM observations demonstrated that microwave-prepared PtRu nanoparticles were narrowly distributed and highly dispersed on the carbon with an average size of 3.9 nm. Electrochemical experiments showed that microwave-synthesized PtRu/carbon catalyst exhibited very high catalytic activity for electro-oxidation of liquid methanol at room temperature. |
| 关 键 词： | 微波 PtRu合金纳米粒子 催化剂 燃料电池 |
| 修稿时间： | 2004-05-18 |
PtRu/Carbon Catalyst: Microwave Polyol Synthesis and Electrocatalytic Activity for Methanol Electrooxidation |
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| CHEN Wei-Xiang,YU Gui-Yan,ZHAO Jie,LEE Jim-Yang and LIU Zhao-Lin. PtRu/Carbon Catalyst: Microwave Polyol Synthesis and Electrocatalytic Activity for Methanol Electrooxidation[J]. Chinese Journal of Inorganic Chemistry, 2004, 20(12): 1467-1470 | |
| Authors: | CHEN Wei-Xiang YU Gui-Yan ZHAO Jie LEE Jim-Yang LIU Zhao-Lin |
| Affiliation: | Department of Chemistry, Zhejiang University, Hangzhou 310027;Singapore-MIT Alliance, National University of Singapore, 117576 Singapore,Department of Chemistry, Zhejiang University, Hangzhou 310027,Department of Chemistry, Zhejiang University, Hangzhou 310027,Singapore-MIT Alliance, National University of Singapore, 117576 Singapore;Department of Chemical and Environmental Engineering, National University of Singapore, 119260 Singapore;Institute of Materials Research and Engineering, 117602 Singapore and Institute of Materials Research and Engineering, 117602 Singapore |
| Abstract: | |
| Keywords: | microwave PtRu nanoparticles catalyst fuel cell |
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