Fabrication of graphene-based porous materials: traditional and emerging approaches

The anisotropic nature of ‘graphenic’ nanosheets enables them to form stable three-dimensional porous materials. The use of these porous structures has been explored in several applications including electronics and batteries, environmental remediation, energy storage, sensors, catalysis, tissue engineering, and many more. As method of fabrication greatly influences the final pore architecture, and chemical and mechanical characteristics and performance of these porous materials, it is essential to identify and address the correlation between property and function. In this review, we report detailed analyses of the different methods of fabricating porous graphene-based structures – with a focus on graphene oxide as the base material – and relate these with the resultant morphologies, mechanical responses, and common applications of use. We discuss the feasibility of the synthesis approaches and relate the GO concentrations used in each methodology against their corresponding pore sizes to identify the areas not explored to date.

Due to their anisotropic nature, graphene nanosheets can be used to form 3-dimensional porous materials using template-free and template-directed methodologies. These fabrication strategies are found to influence the properties of the final structure.