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Biomimetic studies on polyenes
Authors:Moses John E  Baldwin Jack E  Brückner Sébastien  Eade Serena J  Adlington Robert M
Institution:The Dyson Perrins Laboratory, University of Oxford, Oxford, UK OX1 3QY.
Abstract:The crispatenes and SNF4435 C&D are complex polypropionate derived natural products. The core structures of these compounds along with a complex unnatural structure can be easily prepared from a common polyene precursor simply by variation of the reaction conditions. The reaction pathways provide insight into the biosynthesis of these complex natural products.
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