Biomimetic studies on polyenes |
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Authors: | Moses John E Baldwin Jack E Brückner Sébastien Eade Serena J Adlington Robert M |
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Institution: | The Dyson Perrins Laboratory, University of Oxford, Oxford, UK OX1 3QY. |
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Abstract: | The crispatenes and SNF4435 C&D are complex polypropionate derived natural products. The core structures of these compounds along with a complex unnatural structure can be easily prepared from a common polyene precursor simply by variation of the reaction conditions. The reaction pathways provide insight into the biosynthesis of these complex natural products. |
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