Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic-polyoxometalate hybrid compound |
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| Authors: | Bar-Nahum Itsik Neumann Ronny |
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| Institution: | Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel, 76100. |
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| Abstract: | A metal-organic-polyoxometalate hybrid compound with two functional centers consisting of a rhodium(I)bis(diphenylphospine) unit connected through two alkylene bridging groups to a lacunary Keggin type polyoxometalate was synthesized and used as an effective, recyclable hydrogenation catalyst in monophasic and aqueous biphasic reaction modes. |
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