Hindered fluorescence quenching in an insulated molecular wire |
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Authors: | Taylor Peter N Hagan Andrew J Anderson Harry L |
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Institution: | Department of Chemistry, University of Oxford, Dyson Perrins Laboratory, South Parks Road, Oxford, UK OX1 3QY. |
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Abstract: | A 3]rotaxane 2 within 1(2) consisting of an anionic phenylene ethynylene dumbbell 2(4-) threaded through two cationic cyclophanes 1(2+) has been prepared using aqueous Glaser coupling. Stern-Volmer analysis of the fluorescence quenching using three different electron-acceptors (methyl viologen 13(2+), dipropyl-4,4'-bipyridinium disulfonate 14 and anthraquinone-2,6-disulfonate 15(2-)) shows that the threaded cyclophanes inhibit electron-transfer from the excited state of the dumbbell by steric shielding, and by electrostatic shielding in the case of methyl viologen. |
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