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Ir/SiO2 as a highly active catalyst for the selective reduction of NO with CO in the presence of O2 and SO2
Authors:Haneda Masaaki  Yoshinari Tomohiro  Sato Kazuhito  Kintaichi Yoshiaki  Hamada Hideaki
Affiliation:Research Institute for Green Technology, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
Abstract:Coexisting SO2 considerably enhanced the catalytic activity of Ir/SiO2 for NO reduction with CO in the presence of O2 because of the formation of a cis-type coordinated species of NO and CO to one iridium atom ([formula: see text]), a possible reaction intermediate leading to N2 formation.
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