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Construction of a square-planar hydroperoxo-copper(II) complex inducing a higher catalytic reactivity
Authors:Fujii Tatsuya  Naito Asako  Yamaguchi Syuhei  Wada Akira  Funahashi Yasuhiro  Jitsukawa Koichiro  Nagatomo Shigenori  Kitagawa Teizo  Masuda Hideki
Institution:Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya 466-8555, Japan.
Abstract:A novel hydroperoxo-copper(II) complex with a square-planar geometry has been prepared, which has exhibited a higher selectivity and catalytic reactivity for dimethyl sulfide, in contrast to that with a trigonal-bipyramidal one.
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