Molecular tectonics. Dendritic construction of porous hydrogen-bonded networks |
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Authors: | Laliberté Dominic Maris Thierry Sirois Ariane Wuest James D |
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Affiliation: | Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada. |
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Abstract: | Molecules that associate to form porous networks can be made by attaching multiple hydrogen-bonding sites to suitable cores. Pentaerythrityl tetraphenyl ether, a four-armed core, is the progenitor of dendritic derivatives with more arms, including dipentaerythrityl hexaphenyl ether 7. An advantage of such dendritic derivatives is that the resulting networks are held together by larger numbers of intermolecular hydrogen bonds. [structure: see text] |
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