Ultrafast chemistry: cobalt carbonyl-mediated synthesis of diaryl ketones under microwave irradiation |
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| Authors: | Enquist Per-Anders Nilsson Peter Larhed Mats |
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| Affiliation: | Organic Pharmaceutical Chemistry, Department of Medicinal Chemistry, Uppsala Biomedical Center, Uppsala University, P.O. Box 574, SE-751 23 Uppsala, Sweden. |
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| Abstract: | By combining the advantages of metal activation, in situ carbon monoxide delivery, and microwave heating, benzophenones were efficiently synthesized in 6-10 s. These ultrafast carbonylation reactions occur under air by flash heating of aryl iodides in the presence of dicobalt octacarbonyl. [reaction: see text] |
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