Vapor–liquid equilibria for nitrogen with 2-propanol, 2-butanol,or 2-pentanol binary systems |
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Affiliation: | 1. State Key Laboratory of Engines, Tianjin University, Tianjin 300072, China;2. China Automotive Technology & Research Center, Tianjin 300300, China |
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Abstract: | Isothermal vapor–liquid equilibrium (VLE) data were measured for the binary systems of nitrogen with 2-propanol, 2-butanol, or 2-pentanol at temperatures from 333.15 to 393.15 K and pressure up to 100 bar. Henry's constants of nitrogen in these three sec-alcohols were determined by using the Krichevesky–Ilinskaya equation. The experimental VLE data were also correlated by the Peng–Robinson and the Patel–Teja equations of state with various mixing rules. |
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