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Liquid–liquid equilibrium in ternary systems N,N-dimethylformamide + 2-methylpentane + methanol and N,N-dimethylformamide + methylcyclohexane + methanol
Institution:1. Department of Physical Chemistry, Institute of Chemical Technology, Prague, Technická 5, CZ-166 28 Prague 6, Czech Republic;2. Department of Semiconductors, Institute of Physics, Academy of Sciences of the Czech Republic, v. v. i., Cukrovarnická 10, 162 00 Prague 6, Czech Republic;3. Department of Chemical and Biological Engineering, Colorado School of Mines, Golden, CO 80401, USA;4. Department of Chemistry IFM, University of Turin, Via P. Giuria 9, 10125 Torino, Italy;1. Chemistry Department, Da Nang University of Technology, 54 Nguyen Luong Bang, Da Nang, Viet Nam;2. IFP Energies Nouvelles, 1-4 Avenue de Bois-Préau, 92852 Rueil-Malmaison, France;3. Center for Energy Resources Engineering (CERE), Department of Chemical and Biochemical Engineering, Technical University of Denmark, DK-2800 Lyngby, Denmark;1. Department of Engineering Physics, University of Wisconsin – Madison, Madison 53706, USA;2. Department of Materials Science and Engineering, University of Wisconsin – Madison, Madison 53706, USA
Abstract:In the present paper, a study of temperature behaviour of the liquid–liquid equilibrium in ternary systems N,N-dimethylformamide + 2-methylpentane + methanol and N,N-dimethylformamide + methylcyclohexane + methanol. The analysis of critical curves of the liquid–liquid equilibrium by means of the regular solution model was carried out. The acquired predictions were subsequently verified experimentally.
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