Preparation and luminescence of blue-emitting phosphor Ca2PO4Cl:Eu2+ for n-UV white LEDs |
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| Authors: | Ruijin Yu Chongfeng Guo Ting Li Yan Xu |
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| Institution: | 1. College of Science, Northwest A&F University, Yangling, Shaanxi 712100, China;2. National Key Laboratory of Photoelectric Technology and Functional Materials (Culture Base) in Shaanxi Province, National Photoelectric Technology and Functional Materials & Application of Science and Technology International Cooperation Base, Institute of Photonics & Photon-Technology and Department of Physics, Northwest University, Xi''an 710069, China |
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| Abstract: | A series of blue-emitting Ca2 ? xEuxPO4Cl phosphors were synthesized by a solid state method in a reducing atmosphere. The factors those affect the structure and the photoluminescence (PL) intensities of phosphors, including the dosage of chlorine source CaCl2, reaction time and annealing temperature, have been investigated in detail. X-ray diffraction (XRD) and photoluminescence measurements were performed to testify the crystal structure and luminescent properties. The optimal Eu2+ concentration was determined, and the mechanism of the concentration quenching was predominated by dipole–dipole interaction. The present phosphor exhibits a strong absorption in the near-UV region, emits an intense blue emission centered at 451 nm and presents excellent thermal stability, suggesting that the phosphor is competitive as a promising blue-emitting phosphor for near ultraviolet (n-UV) light-emitting diodes (LEDs). |
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