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N-(2-甲基)苯基甘氨酸的三价和四价金属/非金属衍生物(英)
作者姓名:Deepti Joshi  Deepak Pant  Madhup Chandra
作者单位:Chemical Laboratories, D.S.B. Campus, Kumaun University, Nainital 263002, India,Chemical Laboratories, D.S.B. Campus, Kumaun University, Nainital 263002, India,Chemical Laboratories, D.S.B. Campus, Kumaun University, Nainital 263002, India
摘    要:用N-(2-甲基)苯基甘氨酸合成了几种(硼、铝、铁、砷和锑)及四价(硅、钛和硒)金属/非金属衍生物。合成是在苯溶液中采用了金属/非金属的异丙氧基化合物和N-(2-甲基)苯基甘氨酸按1∶1和1∶2的配比完成的。一般情况下,合成的产物均为有色固体,以及在产物中有异丙氧基基团残留而显吸湿性。对所制成的衍生物均采用了共沸混合物分析、元素分析和光谱测定等进行了表征。

关 键 词:金属/非金属  N-(2-甲基)苯基甘氨酸  醇解反应

Trivalent and Tetravalent Metal/Non-Metal Derivatives of N-(2-Methyl) Phenylglycine
Deepti Joshi,Deepak Pant,Madhup Chandra.Trivalent and Tetravalent Metal/Non-Metal Derivatives of N-(2-Methyl) Phenylglycine[J].Chinese Journal of Inorganic Chemistry,2004,20(4):373-380.
Authors:Deepti Joshi  Deepak Pant and Madhup Chandra
Institution:Chemical Laboratories, D.S.B. Campus, Kumaun University, Nainital 263002, India
Abstract:Several trivalent (boron, aluminium, iron, arsenic and antimony) and tetravalent (silicon, titanium and selenium) metal/non-metal derivatives of N-(2-methyl) phenylglycine have been prepared by the interaction of their corresponding isopropoxide with the latter in 1:1 and 1:2 molar ratios in benzene medium. The course of reaction was monitored by estimating the amount of isopropanol liberated in benzene-isopropanol azeotrope in each case.The compounds thus prepared were generally obtained as colored solids and amongst them those containing isopropoxy group (s) were found to be hygroscopic. All these compounds were characterized by azeotrope and elemental analysis, as well as by spectral measurements.
Keywords:metal/non-metal  N-(2-methyl) phenylglycine  alcoholysis reaction
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