| 一个新的噻二唑衍生物H2ADTZ与锰的二维聚合物的合成与晶体结构(英) |
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| 引用本文： | 娄新华,朱玉,高辉,朱爱新,樊耀亭,侯红卫,卢会杰.一个新的噻二唑衍生物H2ADTZ与锰的二维聚合物的合成与晶体结构(英)[J].无机化学学报,2005,21(5):716-720. |
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| 作者姓名： | 娄新华 朱玉 高辉 朱爱新 樊耀亭 侯红卫 卢会杰 |
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| 作者单位： | 1. 郑州大学化学系,郑州,450052
2. 郑州大学化学系,郑州,450052;洛阳大学环境工程与化学系,洛阳,471023 |
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| 基金项目： | 国家自然科学基金资助项目(No.20471053)，国家重点基础研究专项基金资助项目(No.2003CB214500)，郑州大学能源工程资助项目。 |
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| 摘 要： | A new 1,3,4 thiadiazole-derivative ligand 2,5-(s-acetic acid) dimercapto-1,3,4 thiadiazole (H2ADTZ) and its one-dimensional manganese polymer Mn(ADTZ)·4H2O had been synthesized and structurally characterized by X-ray single crystal diffraction in this paper. The Mn(Ⅱ) ion is coordinated with a distorted octahedron by two oxygen atoms from neighboring two deprotonated ligands ADTZ2- and other four oxygen atoms from four coordinated water molecules. The structural feature of the title compound is the formation of one-dimensional manganese chains polymer through the bridging of dioxygen O-O units. In the solid state structure of the complex, one-dimensional manganese chains are joined together by the weak intermolecular hydrogen bonds and vander Waals interactions forming a two-dimensional supramolecular compound. Furthermore, the UV spectra and electro-chemical properties of the title compound were also investigated. CCDC: 260532.
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| 关 键 词： | 锰 聚合物 噻二唑衍生物 氢键 循环伏安 |
| 收稿时间： | 2004/8/22 0:00:00 |
| 修稿时间： | 2004/12/2 0:00:00 |
Synthesis,Crystal Structure and Properties of a New Thiadiazolen Two-dimensional Polymer of H2ADTZ with Mn(Ⅱ) |
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| LOU Xin-Hu,ZHU Yu,Gao Hui,ZHU Ai-Xin,FAN Yao-Ting,HOU Hong-Wei and LU Hui-Jie.Synthesis,Crystal Structure and Properties of a New Thiadiazolen Two-dimensional Polymer of H2ADTZ with Mn(Ⅱ)[J].Chinese Journal of Inorganic Chemistry,2005,21(5):716-720. |
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| Authors: | LOU Xin-Hu ZHU Yu Gao Hui ZHU Ai-Xin FAN Yao-Ting HOU Hong-Wei and LU Hui-Jie |
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| Institution: | Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052;College in Environmental and Chemical Engineering, Luoyang University, Luoyang 471023,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052 and Department of Chemistry, Zhengzhou University, Zhengzhou 450052 |
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| Abstract: | A new 1,3,4 thiadiazole-derivative ligand 2,5-(s-acetic acid) dimercapto-1,3,4 thiadiazole (H2ADTZ)and its one-dimensional manganese polymer Mn(ADTZ). 4H2O had been synthesized and structurally characterized by X-ray single crystal diffraction in this paper. The Mn(Ⅱ) ion is coordinated with a distorted octahedron by two oxygen atoms from neighboring two deprotonated ligands ADTZ2- and other four oxygen atoms from four coordinated water molecules. The structural feature of the title compound is the formation of one-dimensional manganese chains polymer through the bridging of dioxygen O-O units. In the solid state structure of the complex,one-dimensional manganese chains are joined together by the weak intermolecular hydrogen bonds and vander Waals interactions forming a two-dimensional supramolecular compound. Furthermore, the UV spectra and electro-chemical properties of the title compound were also investigated. CCDC: 260532. |
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| Keywords: | Mn(Ⅱ) polymer thiadiazole-derivative hydrogen bonds cyclic voltammetry |
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