Phenylhydrazines. Structure and basicity |
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Authors: | N G Korzhenevskaya V I Rybachenko V V Kovalenko S N Lyashchuk A N Red’ko |
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Institution: | (1) Donbass State Machine-Building Academy, Kramatorsk, 84313, Ukraine |
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Abstract: | The main properties of phenylhydrazines are governed by the p-character of the unshared electron pair of the nitrogen of imino group changing in keeping with sp 3 → sp 2-regibridization of its atomic orbitals under the steric and electronic (-I effect of amino group) effect of substituents. |
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