| CH2(X 3B1)自由基与N2O反应的研究 |
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| 引用本文： | 苏红梅,吴成印,杨继新,钟晋贤,孔繁敖.CH2(X 3B1)自由基与N2O反应的研究[J].物理化学学报,1999,15(6):560-563. |
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| 作者姓名： | 苏红梅 吴成印 杨继新 钟晋贤 孔繁敖 |
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| 作者单位： | The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,Resarch Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085 |
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| 摘 要： |
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| 关 键 词： | C2H N2O 反应通道 TR-FTIRS |
| 收稿时间： | 1998-07-03 |
| 修稿时间： | 1998-10-29 |
Study of the Reaction CH2(X 3B1)+N2O |
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| Su Hong-Mei,Wu Cheng-Yin,Yang Ji-Xin,Zhong Jin-Xian,Kong Fan-Ao.Study of the Reaction CH2(X 3B1)+N2O[J].Acta Physico-Chimica Sinica,1999,15(6):560-563. |
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| Authors: | Su Hong-Mei Wu Cheng-Yin Yang Ji-Xin Zhong Jin-Xian Kong Fan-Ao |
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| Institution: | The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080|Resarch Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085 |
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| Abstract: | The reaction dynamics of methylene radical CH2(X3B1) with N2O was investigated by Time-Resolved Fourier Transform Infrared Spectroscopy(TR-FTIRS). Pure CH2(X3B1) radicalwas produced via laser photolysis of ketene at 351 nm. Nascent viabrationally excited products CO, NO and HCN were observed. Some reaction pathways which may lead to these products were proposed and a possible reaction mechanism was outlined. |
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| Keywords: | 2H' ') C2H" target="_blank">">C2H 2O' ') N2O" target="_blank">">N2O Reaction dynamics TR-FTIRS |
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