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Igepal CO 520/CnH2n+1OH/H2O体系的相行为与结构特性
引用本文:郭荣,张晓红,刘天晴.Igepal CO 520/CnH2n+1OH/H2O体系的相行为与结构特性[J].物理化学学报,1999,15(4):319-326.
作者姓名:郭荣  张晓红  刘天晴
作者单位:Department of Chemistry,Science College,Yangzhou University,Yangzhou 225002
基金项目:国家自然科学基金!29673935
摘    要:随直键醇CnH2n 1OH的链长增加,IgepalCO520/CnH2n 1OH/H2O体系三组分相图中层状液晶区域增加,使得W/O区域上移,W/O区域中最大水增溶量处所需摩尔比CnH2n 1OH/IgepalCO520降低,W/O区域中水的最大增溶量(摩尔分数)却不变.层状液晶中CnH2n 1OH的最佳链长为n>8,W/O区域中CnH2n 1OH的最佳键长为n>10,即能获得比较好的与IgepalCO520的配伍性.

关 键 词:Igepal  CO  520  微乳液  增溶  层状液晶  
收稿时间:1998-05-29
修稿时间:1998-10-12

Phase Behavior and Phase Structure Of lgepal CO 520C_nH(2n 1)OH/H_2O System
Guo Rong, Zhang Xiaohong, liu Tianqing.Phase Behavior and Phase Structure Of lgepal CO 520C_nH(2n 1)OH/H_2O System[J].Acta Physico-Chimica Sinica,1999,15(4):319-326.
Authors:Guo Rong  Zhang Xiaohong  liu Tianqing
Institution:Department of Chemistry,Science College,Yangzhou University,Yangzhou 225002
Abstract:With increasing of n in CnH2n+1 OH, the lamellar liquid crystal region increases and W/O region moves upward in the three components phase diagram, and the maximum water content (molar fraction) solubilized in W/O region is constant but the molar ratio of CnH2m+1 OH/Igepal 520 decreases at maximum water content. The chain length of CnH2n+1 OH is n>8 in the lamellar liquid crystal and n >10 in the W/O region.
Keywords:Igepal CO 520  Microemulsicn  Solubilization  Lainellar liquid crystal
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