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Normal- and Reversed-Phase Behaviour of 16,17-Secoestrone Derivatives on Cyanopropyl-Bonded Silica Gel |
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| Authors: | Ač anski,Marijana M.,Dobrijević , Jelena P.,Redž epović , Azra S.,Vujić , Đ ura N.,Jovanović -Š anta,Suzana S. |
| Affiliation: | 1.Department of Applied and Engineering Chemistry, Faculty of Technology, University of Novi Sad, Bulevar cara Lazara 1, 21000, Novi Sad, Serbia ;2.Institute of Chemistry, Faculty of Science, University of Novi Sad, Trg Dositeja Obradovića 3, 21000, Novi Sad, Serbia ; |
| Abstract: | The retention behaviour of a number of 16,17-secoestrone derivatives has been studied by LC and HPTLC on a polar cyanopropyl-bonded stationary phase using non-aqueous and aqueous-organic mobile phases. The retention behaviour has been discussed in terms of nature of the solute, eluent and stationary phase. The correlation between retention constants of 16,17-secoestrone derivatives obtained from reversed-phases and commercially available ACD log P software (Advanced Chemistry, Toronto, Canada) has also been examined. |
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