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氧化镁的结构与甲烷氧化偶联催化性能
引用本文:甄开吉,李森梓.氧化镁的结构与甲烷氧化偶联催化性能[J].高等学校化学学报,1994,15(6):891-894.
作者姓名:甄开吉  李森梓
作者单位:吉林大学化学系
摘    要:制法不同的MgO对甲烷氧化偶联的催化性能相差悬殊,比表面积、XRD、XPS测试结果表明,在较低的反应温度范围内,比表面积大,则晶格畸变率大、晶粒度小,表面未饱和的配位氧量高的MgO有较好的催化性能。

关 键 词:甲烷  氧化偶联  氧化镁  催化剂  性能

The Stucture of Mgo and Its Catalytic Properties for Oxidation Coupling of Methane
ZHEN Kai-Ji,LI Sen-Zi,BI Ying-Li,WEI Quan,YANG Xiang-Guang.The Stucture of Mgo and Its Catalytic Properties for Oxidation Coupling of Methane[J].Chemical Research In Chinese Universities,1994,15(6):891-894.
Authors:ZHEN Kai-Ji  LI Sen-Zi  BI Ying-Li  WEI Quan  YANG Xiang-Guang
Abstract:A series of MgO catalysts prepared by different methods for the catalytic oxidation coupling of methane were investigated.The specific surface area,XRD and XPS measurement results reveal that the catalysts with larger specific surface area,larger lattice distortion,Iess crystal dimension and higher amount of surface unsaturated coordinated oxygen can give higher catalytic activity for the reaction mentioned above at lower temperatures.
Keywords:Oxidation coupling of methane  MgO  Properties of catalysts  
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