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The Electronic Structure of Vinyl Ethers and Sulfides with Interrupted Conjugation Examined by Photoelectron Spectroscopy |
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| Authors: | Christopher Batich Edgar Heilbronner Clayton B Quinn John R Wiseman |
| Abstract: | Photoelectron spectroscopy has been used to examine the consequences of steric inhibition of conjugation in a distorted vinyl sulfide and vinyl ether. Based upon the degree of interaction a deviation from coplanarity of 70°–75° is calculated for 9-oxabicyclo3.3.1]non-1-ene ( 3 ) and approximately 75°–80° for the sulfur analog 6 . |
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