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Catalytic and thermal transformations of methyl- and isopropylcyclobutanes
Authors:A. L. Lapidus  A. V. Dolidze  Kh. I. Areshidze  Ya. T. Éidus
Affiliation:(1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR;(2) P. G. Melikishvili Institute of Physical and Organic Chemistry, Academy of Sciences of the Georgian SSR, USSR
Abstract:Conclusions The thermal decomposition of the methyl- and isopropylcyclobutanes in the presence of quartz powder proceeds only with cleavage of the ring at two bonds, while in the presence of amorphous aluminosilicate and zeolite NM the additional reactions of ring opening, cleavage of groups containing one carbon atom, and hydrogen redistribution take place.Translated from Izvestya Akademii Nauk SSSR, Seriya Khimieheskaya, No. 1, pp. 170–172, January, 1973.
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