Catalytic and thermal transformations of methyl- and isopropylcyclobutanes |
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Authors: | A. L. Lapidus A. V. Dolidze Kh. I. Areshidze Ya. T. Éidus |
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Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR;(2) P. G. Melikishvili Institute of Physical and Organic Chemistry, Academy of Sciences of the Georgian SSR, USSR |
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Abstract: | Conclusions The thermal decomposition of the methyl- and isopropylcyclobutanes in the presence of quartz powder proceeds only with cleavage of the ring at two bonds, while in the presence of amorphous aluminosilicate and zeolite NM the additional reactions of ring opening, cleavage of groups containing one carbon atom, and hydrogen redistribution take place.Translated from Izvestya Akademii Nauk SSSR, Seriya Khimieheskaya, No. 1, pp. 170–172, January, 1973. |
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