Synthesis and some transformations of functionally substituted lactones |
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Authors: | A. A. Avetisyan A. G. Alvandzhyan T. A. Kostanyan M. M. Bidar |
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Affiliation: | 1.Erevan State University,Erevan,Armenia |
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Abstract: | Reactions of functionally substituted unsaturated five- and six-membered cyanolactones with α- and β-hydroxy ketones in the presence of sulfuric acid gave substituted 2-oxofuran- and 2-oxopyran-3-carboxamides. Hydrolysis of some keto amides thus obtained afforded the corresponding carboxylic acids, and reactions with hydrazines and semicarbazides led to hydrazones and semicarbazones at the side-chain oxo group. |
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