Decomposition of hydrotrioxides catalyzed by carboxylic acids期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Decomposition of hydrotrioxides catalyzed by carboxylic acids

Authors:	V. V. Shereshovetz N. N. Kabalnova N. M. Korotaeva V. D. Komissarov

Affiliation:	(1) Institute of Chemistry, 450054 Ufa, USSR

Abstract:	Carboxylic acids (HCOOH, CH₃COOH, CH₂ClCOOH, CCl₃COOH, CF₃COOH and C₄H₉COOH) are shown to increase the firstorder effective rate constant of chemiluminescence quenching (k_q) in the decomposition of hydroxides Me₂C(OH)OOOH and Me₂CHOC(OOOH)Me₂. With decreasing pK_a of an acid, its catalytic effect on k_q grows. , HCOOH, CH₃COOH, CH₂ClCOOH, CCl₃COOH, CF₃COOH, C₄H₉COOH () Me₂C(OH)OOOH Me₂CHOC(OOOH)Me₂. .

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