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三元共聚物饱和红色电致发光研究
引用本文:侯林涛,侯琼,彭俊彪,曹镛.三元共聚物饱和红色电致发光研究[J].物理学报,2005,54(11):5377-5381.
作者姓名:侯林涛  侯琼  彭俊彪  曹镛
作者单位:(1)华南理工大学高分子光电材料及器件研究所,广州 510640; (2)华南理工大学高分子光电材料及器件研究所,广州 510640;华南理工大学特种功能材料及其制备新技术教育部重点实验室,广州 510640
基金项目:国家自然科学基金(批准号:90201023)、 “973”项目资助(批准号:2002CB613405)和教育 部重点基金资助
摘    要:研究了高分子电致发光器件中阳极和阴极对三元共聚物饱和红色发光性能的影响.结果表明 ,在二元共聚基础上,引入空穴载流子传输基团可以改善器件的发光效率,对PFO-5Cz-15DB T三元共聚物,在6.5V电压下,外量子效率达到1.49%,亮度为448cd/m2,EL光 谱峰值位于657nm,色度坐标x=0.69,y=0.30. 关键词: 阴极材料 电致发光 发光二极管 聚芴

关 键 词:阴极材料  电致发光  发光二极管  聚芴
文章编号:1000-3290/2005/54(11)/5377-05
收稿时间:3/1/2005 12:00:00 AM
修稿时间:2005-03-012005-04-19

Performance of polymer light-emitting diodes with saturated red-emitting poly(fluorine-co-4,7-dithien-2-yl-2,1,3-benzothiadiazole-carbazole or triphenylamine)
Hou Lin-Tao,Hou Qiong,Peng Jun-Biao,Gao Yong.Performance of polymer light-emitting diodes with saturated red-emitting poly(fluorine-co-4,7-dithien-2-yl-2,1,3-benzothiadiazole-carbazole or triphenylamine)[J].Acta Physica Sinica,2005,54(11):5377-5381.
Authors:Hou Lin-Tao  Hou Qiong  Peng Jun-Biao  Gao Yong
Institution:1.Institute of Polymer Optoelectronic Material and Devices, South China University of Technology, Guangzhou 510640, China; 2.Key Laboratory of Specially Functional Materials and Advanced Manufacturing Technology, South China University of Technology, Guangzhou 510640, China
Abstract:Since electron or hole injection is a limiting factor for most electroluminescent polymers, a matching of the work function of cathodes and anodes and the LUMO\HOMO energy level of polymers is one of the important factors for high performance polymer light emitting devices. In this paper, we report the effect of the cathodes on the performance of the device based on saturated red emitter, three-component copolymer poly (fluorine-co-4, 7-dithien-2-yl-2, 1,3-benzothiadiazole-carbazole or triphenylamine) copolymers. By thermal deposition in combination with spin-coating of electron injection layer, we investigated the influence of various cathode meterials with different ionization potentials in order to optimize the balance of the electron and hole injection. The external quantum efficiency reached 1.49% with luminance 466cd/m2,the EL spectrum peak is located at 657nm with the color coordinate: x=0.69, y=0.30 for PFO-5Cz-15DBT.
Keywords:cathode materials  electroluminescence  organic light-emitting diode s  polyfluorene copolymers
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