RAMAN STUDY ON $X_i^-$(Pb) CENTERS IN SINGLE CRYSTALS OF ALKALI HALIDES DOPED WITH LEAD |
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Institution: | Department of Physics, Shaanxi Normal University, Xi'an 710062, China |
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Abstract: | Low frequency modes were observed in a series of alkali halides doped with lead after X-irradiation at 77K. The peak positions of the Raman signals are at 34cm-1 for NaCl:Pb2+, 30cm-1 for KCl:Pb2+,28cm-1 for RbCl:Pb2+ and 22cm-1 for KBr:Pb2+. They are assigned to the inelastic light scattering caused by the local vibration of $X^-_i$(Pb+) center, which consists of an interstitial halogen ion stabilized by a substitutional ion Pb+ . Polarized Raman measurements and Behavior Typer(BT) analysis show that the symmetry of the $X^-_i$ (Pb+) center belongs to the point group C3v. A structure model of the $X^-_i$ (Pb+) center is proposed based on the Raman data and the result of BT analysis. |
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