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In-Situ Spectroelectrochemical Measurement of Azobenzene Containing Self-Assembled Monolayers |
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| Authors: | R.Wang T.Iyoda D.A.Tryk K.Hashimoto Akira Fujishima I.Bae D.A.Scherson |
| Affiliation: | 1. Department of Applied Chemistry, Faculty of Engineering, The University of Tokyo, Hongo, Bunkyoku, Tokyo, 113, Japan;2. Photochemical Conversion Materials Project, Kanagawa Academy of Science and Technology Laboratory, 1583, liyama, Atsugi, Kanagawa 243-02, Japan;3. Case Center for Electrochemical Sciences and the Department of Chemistry, Case Western Reserve Uiversity, Ohio 44106, U. S. A |
| Abstract: | The electrochemical behavior of an azobenzene containing self-assembled monolayer (SAM) has been examined by means of in-situ Fourier transform infrared reflection absorption (FTIRRA) spectroscopy. The electrochemical reduction product of azobenzene has been confirmed to be hydrazobenzene. A stable and reversible process in both electrochemistry and architecture has been found in the monolayer film. |
| Keywords: | Azobenzene Self-assembled monolayer FTIR In-situ measurement |
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