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Synthesis and characterization of barbituric and thiobarbituric acid complexes
Authors:Mamdouh S Masoud  Ahmed M Heiba  Fathy M Ashmawy
Institution:(1) Faculty of Science, Chemistry Department, Alexandria, Egypt;(2) Faculty of Science, Chemistry Department, Tanta
Abstract:Summary Synthesis of barbituric and thiobarbituric acid complexes derived from cobalt(II), nickel(II) and copper(II) salts were carried out. The elemental analyses suggest a range of stoichiometries, 1ratio1, 1ratio2 and 1ratio3. Electronic spectra and magnetic susceptibility measurements were used to infer the structures. The i.r. spectra of the ligands and their complexes are used to identify the type of bonding.
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