Aryloxide-based multidentate ligands for early transition metals and f-element metals |
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Authors: | Hiroyuki Kawaguchi Tsukasa Matsuo |
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Institution: | Coordination Chemistry Laboratories, Institute for Molecular Science, Myodaiji, Okazaki 444-8787, Japan |
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Abstract: | This article presents an overview of the chemistry of early transition metal and f-element complexes stabilized by aryloxide-based multidentate ligands. Preparations and reactivity studies of these compounds are discussed. The presence of the bridging units in this ligand system imposes a strong geometry constraint to the aryloxide groups, which leads the way to novel patterns of structure and reactivity. |
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Keywords: | Aryloxide complexes Multidentate ligands Chelate effect Early transition metals f-Element metals |
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